STUDI ADSORPSI CONGO RED PADA KITOSAN BERBASIS SELONGSONG PUPA BLACK SOLDIER FLY

Authors

  • Linda Hevira Universitas Mohammad Natsir Bukittinggi, Indonesia

DOI:

https://doi.org/10.1144/jscpr.v2i1.530

Keywords:

Chitosan; Black Soldier Fly; Congo Red; Adsorption; Liquid Waste

Abstract

Pollution of liquid waste containing synthetic dyes is an environmental problem that is also relevant in the industrial and pharmaceutical laboratories. One of these dyes is Congo Red, which is stable, difficult to degrade, and has the potential to cause negative impacts on the aquatic environment. This study aims to produce the ability of chitosan which is generally synthesized from shrimp shells, this time synthesized from the pupa sheath of the Black Soldier Fly (Hermetia illucens). The adsorption test was carried out in batches with variations in pH, contact time, and initial concentration of the dye. Chitosan-BSF before and after absorbing Congo Red was characterized using FTIR and SEM-EDS. The results showed that the adsorption process was greatly influenced by the environmental pH and the pHPZC value of chitosan. The adsorption percentage increased at pH below pHPZC due to the electrostatic interaction between the chitosan surface which produces a positive signal and the Congo Red molecule which produces a negative signal. Contact time affected the rate of achieving adsorption equilibrium, while increasing the initial concentration tended to decrease the adsorption percentage. These results indicate that chitosan from Black Soldier Fly pupae casings has the potential to be an alternative adsorbent that has added value and is environmentally friendly and supports the principle of the desire for dye waste processing.

Downloads

Download data is not yet available.

References

Afkar, K., Masrufah, A., Fawaid, A. S., Alvarizi, W., Khoiriyah, L., Khoiriyah, M., Kafi, A., Faradilla, R. S., Amsah, R., Hidayah, N. N., Salsabella, A., Ayu, D., Nazwa, R., Fadila, S. N., Eka, U., Sari, K., Naim, I., Nur, S., Itsnaini, R., & Ramadhan, M. N. (2020). Budidaya Maggot Bsf (Black Soldier Fly) Sebagai Pakan Alternatif Ikan Lele (Clarias Batracus) Di Desa Candipari, Sidoarjo Pada Program Holistik Pembinaan Dan Pemberdayaan Desa (Php2D). Journal of Science and Social Development, 3, 10–16.

da Silva Alves, D. C., Healy, B., Pinto, L. A. d. A., Cadaval, T. R. S., & Breslin, C. B. (2021). Recent developments in Chitosan-based adsorbents for the removal of pollutants from aqueous environments. Molecules, 26(3). https://doi.org/10.3390/molecules26030594

Dompeipen, E. J. (2017). Isolasi Dan Identifikasi Kitin Dan Kitosan Dari Kulit Udang Windu (Penaeus Monodon) Dengan Spektroskopi Inframerah. Majalah BIAM, 13(1), 31–41.

Fauzia, S., Furqani, F., Zein, R., & Munaf, E. (2015). Adsorption and reaction kinetics of tatrazine by using Annona muricata L seeds. Journal of Chemical and Pharmaceutical Research, 7(1), 573–582.

Grabi, H., Derridj, F., Lemlikchi, W., & Guénin, E. (2021). Studies of the potential of a native natural biosorbent for the elimination of an anionic textile dye Cibacron Blue in aqueous solution. Scientific Reports, 11(1), 1–13. https://doi.org/10.1038/s41598-021-88657-y

Handayani, T., Ramadhani, P., & Zein, R. (2024). Modelling studies of methylene blue dye removal using activated corn husk waste : Isotherm , kinetic and thermodynamic evaluation. South African Journal of Chemical Engineering, 47(January), 15–27.

Harja, M., Buema, G., & Bucur, D. (2022). Recent advances in removal of Congo Red dye by adsorption using an industrial waste. Scientific Reports, 12(1), 1–18. https://doi.org/10.1038/s41598-022-10093-3

Hevira, L., Ighalo, J. O., & Sondari, D. (2025). Adsorption indigo carmine using chitosan from black soldier fly ( Hermetia illucens L .): Insights into scalable application in real wastewater systems. Inorganic Chemistry Communications, 174(P1), 114011. https://doi.org/10.1016/j.inoche.2025.114011

Hevira, L., Ighalo, J. O., Sondari, D., & Hanifah, A. S. (2025). Evaluating the efficiency and scalability of chitosan from black soldier fly in removing Congo red from wastewater. Bioresource Technology Reports, 30(September 2024), 102132. https://doi.org/10.1016/j.biteb.2025.102132

Lagat, M. K., Were, S., Ndwigah, F., Kemboi, V. J., Kipkoech, C., & Tanga, C. M. (2021). Antimicrobial activity of chemically and biologically treated chitosan prepared from black soldier fly (Hermetia illucens) pupal shell waste. Microorganisms, 9(12), 1–16. https://doi.org/10.3390/microorganisms9122417

Lin, Y. S., Liang, S. H., Lai, W. L., Lee, J. X., Wang, Y. P., Liu, Y. T., Wang, S. H., & Lee, M. H. (2021). Sustainable extraction of chitin from spent pupal shell of black soldier fly. Processes, 9(6), 1–9. https://doi.org/10.3390/pr9060976

Liu, S., Ding, Y., Li, P., Diao, K., Tan, X., Lei, F., Zhan, Y., Li, Q., Huang, B., & Huang, Z. (2014). Adsorption of the anionic dye Congo red from aqueous solution onto natural zeolites modified with N,N-dimethyl dehydroabietylamine oxide. Chemical Engineering Journal, 248, 135–144. https://doi.org/10.1016/j.cej.2014.03.026

Mahmood, S., Zurbrügg, C., Tabinda, A. B., Ali, A., & Ashraf, A. (2021). Sustainable Waste Management at Household Level with Black Soldier Fly Larvae (Hermetia illucens). Sustainability, 13(9722), 1–18. https://www.mdpi.com/2071-1050/13/17/9722

Nugrahati, C. N. A., & Nugroho, R. A. (2024). Lauric acid of black soldier fly ( Hermetia illucens L .) larvae oil as cosmetic ingredient. Biology Education, 21(1), 14–19.

Septiani, W., Rachmawati, R., & Zulfikar, M. A. (2023). Adsorpsi Zat Warna Tekstil Direct Blue 14 Menggunakan Kitosan Termodifikasi Dan Komposit Kitosan Termodifikasi Bentonit Adsorption Of Direct Blue 14 Textile Dye By Modified Chitosan And Modified Chitosan Bentonite Composites. 27–36.

Soetemans, L., Uyttebroek, M., & Bastiaens, L. (2020). Characteristics of chitin extracted from black soldier fly in different life stages. International Journal of Biological Macromolecules, 165, 3206–3214. https://doi.org/10.1016/j.ijbiomac.2020.11.041

Sulistiawaty, L., Foliatini, Nurdiani, & Puspita, F. (2022). Isolasi dan Karakterisasi Kitin dan Kitosan dari Pupa Black Soldier Fly ( BSF ). Warta Akab, 46(1), 56–62.

Susilo, H., Nurmayulis, N., Syahbana, M. A., & Sodiq, A. H. (2024). The Potential of Frass BSF as an Organic Fertilizer for Making Sustainable Agriculture a Reality. Jurnal Biologi Tropis, 24(2), 209–215. https://doi.org/10.29303/jbt.v24i2.6782

Triunfo, M., Tafi, E., Guarnieri, A., Salvia, R., Scieuzo, C., Hahn, T., Zibek, S., Gagliardini, A., Panariello, L., Coltelli, M. B., De Bonis, A., & Falabella, P. (2022). Characterization of chitin and chitosan derived from Hermetia illucens, a further step in a circular economy process. Scientific Reports, 12(1), 1–18. https://doi.org/10.1038/s41598-022-10423-5

Wardhana, A. (2016). Black Soldier Fly (Hermetia illucens) as an Alternative Protein Source for Animal Feed. WARTAZOA. Indonesian Bulletin of Animal and Veterinary Sciences, 26(2), 069–078. https://doi.org/10.14334/wartazoa.v26i2.1218

Zein, R., Satrio Purnomo, J., Ramadhani, P., Safni, Alif, M. F., & Putri, C. N. (2023). Enhancing sorption capacity of methylene blue dye using solid waste of lemongrass biosorbent by modification method. Arabian Journal of Chemistry, 16(2), 104480. https://doi.org/10.1016/j.arabjc.2022.104480

Downloads

Published

2026-02-10

How to Cite

Linda Hevira. (2026). STUDI ADSORPSI CONGO RED PADA KITOSAN BERBASIS SELONGSONG PUPA BLACK SOLDIER FLY . Journal of Science and Clinical Pharmacy Research, 2(1), 106–119. https://doi.org/10.1144/jscpr.v2i1.530